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Citation: Jiang Dian-Lu, Yang Wei-Hua, Tong Ru-Ting. The Preparation and Electrochemical Characterization of Self-assembled Membrane Modified Hangning Mercury Drop Electrod[J]. Acta Physico-Chimica Sinica, ;2000, 16(03): 258-262. doi: 10.3866/PKU.WHXB20000313 shu

The Preparation and Electrochemical Characterization of Self-assembled Membrane Modified Hangning Mercury Drop Electrod

1.
Department of Chemistry,Hebei Normal University,Shijiazhuang 050016

Received Date: 21 June 1999
Available Online: 15 March 2000

The electrochemical behavior of self-assembled n-dodecanethiol monolayer and n-dodecanethiol/phosphatidylcholine hybrid bilayer modified HMDE in different concentration of Fe(CN)63-/4- solutions has been studied by using cyclic voltammetry and electrochemical impedance spectroscopy measurements. The equivalent circuit of different system have been put forward. We also calculate the normal electron tunneling rate constant k0 and the apparent thickness d of the membrane.
- Hanging mercury drop electrode(HMDE),
- Self-assembled monolayer,
- Self-assembled bilayer
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