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Citation: Yi Ping-Gui, Shang Zhi-Cai, Yu Qing-Sen, Mei Ming-Hui, Lin Rui-Sen. Chemical Calibration for Cooling Constants of Conduction Calorimeter[J]. Acta Physico-Chimica Sinica, ;2000, 16(01): 87-92. doi: 10.3866/PKU.WHXB20000117 shu

Chemical Calibration for Cooling Constants of Conduction Calorimeter

1.
Department of Chemistry,Zhejiang University,Hangzhou 310027

Received Date: 29 March 1999
Available Online: 15 January 2000

A new chemical method to calibrate the instrument constants of conduction calorimeter, including the cooling constant a of thermal system and the cooling constant β of thermal element which are related with thermal conductivity of the thermal system, has been proposed on the basis of the single parameter or double parameters theoretical model of conduction calorimeter and thermokinetic equation of chemical reaction. This method has been applied to calibrate RD496 II microcalorimeter，and a significant result has been obtained.
- Thermokinetics,
- Conduction calorimeter,
- Instrument constant
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