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Citation: Zhang Yan, Xiao Xiang-Zhu, Feng Yu-Qi, Da Shi-Lu, Qiu Jian-Qing, Ye Chao-Hui. Preparation and Nuclear Magnetic Resonance Characterizations of a Silica-bonded Calix[4]arene Stationary Phase[J]. Acta Physico-Chimica Sinica, ;2000, 16(01): 65-69. doi: 10.3866/PKU.WHXB20000113 shu

Preparation and Nuclear Magnetic Resonance Characterizations of a Silica-bonded Calix[4]arene Stationary Phase

1.
Laboratory of Magnetic Resonance and Atomic and Molecular Physics,Wuhan Institute of Physics and Mathematics,The Chinese Academy of Sciences,Wuhan 430071

Received Date: 11 February 1999
Available Online: 15 January 2000

A new method was used to prepare a calix [4] arene-bonded silica stationary phase. The chemically modified calix[4] arene 1 was attached to silica gel via the silane coupling reagent γ-(ethylenediamino ) -propyl-triethoxyl-silane. The resulting bonded phase was characterized by 29 Si and 13C cross polarization/magic angle spinning(CP/MAS) nuclear magnetic resonance(NMR) techniques.
- Silica-bonded calixarenes,
- Stationary phase,
- CP/MAS,
- NMR
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