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Citation: Dong Feng, Zou Sheng-Li, Chen Hong, Li Xue-Chu, Lou Nan-Quan. Rotational Inelastic Collisions of NH₂(A²A₁,(0,9,0)) under Single Collisional Condition[J]. Acta Physico-Chimica Sinica, ;1999, 15(09): 812-818. doi: 10.3866/PKU.WHXB19990908 shu

Rotational Inelastic Collisions of NH₂(A²A₁,(0,9,0)) under Single Collisional Condition

1.
State Key Laboratory of Molecular Reaction Dynamics,Dalian Institute of Chemical Physics,Chinese Academic of Sciences,Dalian 116023

Received Date: 22 January 1999
Available Online: 15 September 1999

The study on the rotational state to state energy transfer (RSET) of asymmetric top molecule NH 2 (～A2A1) (0,9,0) under molecular beam condition is reported in detail, including a systematic study of the relative population transferred as functions of initially excited quantum state, different Ka, nuclear-spin, and even spin-doublet. Some propensity rules were obtained directly, and the relation of the mechanism of RSET with EGL (energy gap law) and AMT(angular momentum transfer) was discussed.
- NH2 rotational state-to-state energy transfer,
- Propensity rule,
- Energy gap law,
- Angular momentum transfer
  ,
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Rotational Inelastic Collisions of NH2(A2A1,(0,9,0)) under Single Collisional Condition

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通讯作者: 陈斌, bchen63@163.com

Rotational Inelastic Collisions of NH₂(A²A₁,(0,9,0)) under Single Collisional Condition