引用本文:
王晓玲, 索全伶, 王一兵, 孙杰. FeCo2(CO)7(μ3-S)(O[P(SCH2)2]2)的合成与晶体结构[J]. 物理化学学报,
1999, 15(08): 757-760.
doi:
10.3866/PKU.WHXB19990817
Citation: Wang Xiao-Ling, Suo Quan-Ling, Wang Yi-Bing, Sun Jie. Synthesisi and Crystal Structure of FeCo2(CO)7(μ3-S)(O[P(SCH2)2]2)[J]. Acta Physico-Chimica Sinica, 1999, 15(08): 757-760. doi: 10.3866/PKU.WHXB19990817
Citation: Wang Xiao-Ling, Suo Quan-Ling, Wang Yi-Bing, Sun Jie. Synthesisi and Crystal Structure of FeCo2(CO)7(μ3-S)(O[P(SCH2)2]2)[J]. Acta Physico-Chimica Sinica, 1999, 15(08): 757-760. doi: 10.3866/PKU.WHXB19990817
English
Synthesisi and Crystal Structure of FeCo2(CO)7(μ3-S)(O[P(SCH2)2]2)
Abstract:
The reaction of FeCo2CO9(μ3-S ) with O [P(SCH2)2]2 ligand in mixed solvents of hexane and dichloromethane at 50℃ leads to the compound FeCo2 CO7 (μ3)-S) (O [PSCH22]2). The compound has been characterized by element analysis, IR, 1H NMR, MS spectra and a single crystal X-ray structure determination. Its structure consists, of a distorted tetrahedral core FeCo2S in which the Co(1), Co(2), Fe, and S atoms occupy a vertex of the tetrahedron respectively, and the P atoms of O [PSCH22]2 bonded to two Co atoms in their axial positions.
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Key words:
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Synthesis
- / Fe-Co Cluster
- / Crystal structure
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