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Citation: Jiang Li-Zhong, Zhou Ming-Fei, Liu Xian-Nian, Qin Qi-Fei. CeO₂ Thin Film as a Lithium-ion-storage Mterial Fabricted by Pulsed Laser Deposition[J]. Acta Physico-Chimica Sinica, ;1999, 15(08): 752-756. doi: 10.3866/PKU.WHXB19990816 shu

CeO₂ Thin Film as a Lithium-ion-storage Mterial Fabricted by Pulsed Laser Deposition

1.
Institute of Laser Chemistry,Fudan University,Shanghai 200433

Received Date: 16 November 1998
Available Online: 15 August 1999

CeO2 then films have been fabricated on stainless steel substrate heated at 700℃ in an oxygen ambient by pulsed laser deposition. SEM showed that as-deposited films are mainly com- posed of uniform nanocrystalline particles. Films were characterized by X-ray diffraction from which the oxygen deficient polycrystalline Ce6O11, with a modified monoclinic structure has been demonstrated. The electrochemical properties of the films were measured with cyclic voltammetry and galvonostatic charge /discharge techniques. Our results showed that the CeO2 film exhibits od cyclibility with a reversible capacity of 45mC. cm-2(in the range of 0.1 to 1.5V at current density 40μA•cm-2). It can be suggested that CeO2 thin film is suitable for the anode of Li rechargeable microbattery.
- Pulsed laser deposition,
- Lithium battery,
- Lithium-ion embeding,
- CeO2 thin film
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

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CeO2 Thin Film as a Lithium-ion-storage Mterial Fabricted by Pulsed Laser Deposition

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CeO₂ Thin Film as a Lithium-ion-storage Mterial Fabricted by Pulsed Laser Deposition