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Citation: Su Hong-Mei, Wu Cheng-Yin, Yang Ji-Xin, Zhong Jin-Xian, Kong Fan-Ao. Study of the Reaction CH₂(X ³B₁)+N₂O[J]. Acta Physico-Chimica Sinica, ;1999, 15(06): 560-563. doi: 10.3866/PKU.WHXB19990615 shu

Study of the Reaction CH₂(X ³B₁)+N₂O

1.
The State Key Laboratory of Molecular Reaction Dynamics,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080

Received Date: 3 July 1998
Available Online: 15 June 1999

The reaction dynamics of methylene radical CH2(X3B1) with N2O was investigated by Time-Resolved Fourier Transform Infrared Spectroscopy(TR-FTIRS). Pure CH2(X3B1) radicalwas produced via laser photolysis of ketene at 351 nm. Nascent viabrationally excited products CO, NO and HCN were observed. Some reaction pathways which may lead to these products were proposed and a possible reaction mechanism was outlined.
- C₂H,
- N₂O,
- Reaction dynamics,
- TR-FTIRS
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Study of the Reaction CH2(X 3B1)+N2O

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通讯作者: 陈斌, bchen63@163.com

Study of the Reaction CH₂(X ³B₁)+N₂O