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Citation: Cai Yong, Zhu Xi-Wen, Yan Min, Chen Yong-Tai, Gao Ke-Lin. Chemical Reactions of Transition-metals with CO[J]. Acta Physico-Chimica Sinica, ;1999, 15(02): 162-166. doi: 10.3866/PKU.WHXB19990213 shu

Chemical Reactions of Transition-metals with CO

1.
Laboratory of Magnctic Resonance and Atomic and Molecular Physics,Wuhan Institute of Physics and Mathematics,The Chinese Academy of Sciences,Wuhan 430071

Received Date: 24 April 1998
Available Online: 15 February 1999

Chemical reactions of cluster ions of transition-metals (Fe2+ Co2+ Ni2+) with CO were studied by using an ion trap affixed with a laser ablation source. The experiments indicate that Co2+ is more reactive than Fe2+ and Ni2+ when they react with CO molecule, and the reaction rates are independent on CO pressure. The results are in agreement with the theoretical simulation and the previous data.
- Ion trap,
- Chuster,
- Chemisorption
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