Citation:
Li Bin, Sui Zhi-Tong. Glass Crystallization Mechanism of CaO-M -Fe2O3-Al2O3-SiO2 Slag[J]. Acta Physico-Chimica Sinica,
;1998, 14(07): 645-648.
doi:
10.3866/PKU.WHXB19980714
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The glass-ceramics of CaO-M -Fe2O3-Al2O3-SiO2 slag was prepared. Crystallization kinetics parameter and activation energy of the system were investigated by the kinetics theory and DTA technique. The crystallization mechanism of two-dimensional crystal growth and m=n=2 was determined. The activation energy calculated was 272.6 kJ•mol-1. The microstructure obtained by the SEM technique indicated that the mechanism of crystal growth is in od agreement with the result predicted.
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Keywords:
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Slag
, - Glass,
- Crystallization mechanism,
- Kinetics
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