Citation:
Yu Jian-Feng, Qin Du-Jie, Wu Tong-Hao, Wang Guo-Jia, Sun Jia-Zhong. The Repair Effect of Transition-Metal lons on the Lacunary Heteropoly Complexes with Keggin Structure[J]. Acta Physico-Chimica Sinica,
;1998, 14(05): 435-438.
doi:
10.3866/PKU.WHXB19980510
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The 4th period transition-metal lacunary monosubstituted molybdophosphoric and tungstophosphoric complexes with Keggin structrue were synthesized. The synthesis conditions were discussed. The repair effect of the changing of the transition- metal ions electronic configuration on the substituted ligands was characterizated by the vibration of P-O.
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