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Citation: Zhou Zhi-Fen, Lin Hua-Kuan, Li Su-Qi, Zhu Shou-Rong, Chen Rong-Ti. Study of Thermochemical Properties of Cu(II)-α,α'-bipyridyl-macrocyclic Dioxotetraamine Ternary Systems[J]. Acta Physico-Chimica Sinica, ;1998, 14(04): 343-348. doi: 10.3866/PKU.WHXB19980411 shu

Study of Thermochemical Properties of Cu(II)-α,α'-bipyridyl-macrocyclic Dioxotetraamine Ternary Systems

1.
Department of Chemistry,Nankai University,Tianjin 300071

Received Date: 28 July 1997
Available Online: 15 April 1998

Thermal effects of coordination reaction of Cu(Ⅱ )-α,α'-bipyridyl-macrocyclic dioxotetraaming ternary complex compounds have been determined in aqueous solution at 25.0±0.1℃ and I=0.1 mol•dm-3 KNO3 by means of model RD-1 automatic conduction calorimeter. Linear thermodynamic function relationships have been found to exist in this ternary system. Thermodynamic properties of Cu(Ⅱ)-bipy/phen-HRTADO ternary systems have been compared and discussed. The effects of substituents and stacking of aromatic ring to the thermodynamic properties Cu(Ⅱ)-bipy/phen-HRTADO ternary systems also have been discussed.
- Copper(II),
- α,α-Bipyridyl,
- Macrocyclic dioxotetrammine,
- Thermochemical property
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