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Citation: Yan Jiang-Li, Mao Xi-An, Shen Lian-Fang. Enthalpy for the Conformational Exchange of the Complex of Ferroceno-seleno-platinum Studied with ¹H NMR[J]. Acta Physico-Chimica Sinica, ;1997, 13(09): 853-856. doi: 10.3866/PKU.WHXB19970916 shu

Enthalpy for the Conformational Exchange of the Complex of Ferroceno-seleno-platinum Studied with ¹H NMR

1.
State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics,Wuhan Institute of Physics,The Chinese Academy of Sciences,Wuhan 430071,People's Republic of China

Received Date: 6 December 1996
Available Online: 15 September 1997

The intramolecular conformational exchange thermodynamics of cis-PtCl[1,1'bis(undecenylseleno)ferrocene](B11SeFcPt) in CDCl3 solution was studied by one dimensional proton NMR． The chemical equilibrium constants were obtained directly from the integration of the 1H NMR spectra and the enthalpy as a function of temperature for the conformational exchange of B11SeFcPt was calculated from the equilibrium constant.
- Conformational exchange enthalpy,
- ¹H NMR,
- Selenoferrocene complex of PtCl₂
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Enthalpy for the Conformational Exchange of the Complex of Ferroceno-seleno-platinum Studied with 1H NMR

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Enthalpy for the Conformational Exchange of the Complex of Ferroceno-seleno-platinum Studied with ¹H NMR