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Citation: Yan Zhan-Xian, Zhou Xiao-Qing, Dai Wei, Chen Ci-Xing. Theoretical Research on Optical,Thermal and Magnetic Properties of Ni(pz)₄Cl₂ Complex[J]. Acta Physico-Chimica Sinica, ;1996, 12(11): 995-1000. doi: 10.3866/PKU.WHXB19961108 shu

Theoretical Research on Optical,Thermal and Magnetic Properties of Ni(pz)₄Cl₂ Complex

1.
Department of Physics,Hunan Jishou University,Jishou 416000

Received Date: 29 May 1996
Available Online: 15 November 1996

In this paper, we have calculated analyzed theoretically the absorption spectra, the low-temperature Schottky heat capacity and the paramagnetic susceptibility of Ni2+ ions in Ni(pz)4Cl2 (pz=Pyrazole) complex, by using the complete configuration mixing unified crystal field theory for d8(D4h*), and the theoretical results agree with the experimental data very well. Thus we can give a complete and reasonable theortical interpretation of the optical, thermal and magnetic properties of the Ni2+ ions in Ni(pz)4Cl2 complex.
- Ni(pz)₄Cl₂,
- Absorption spectra,
- Susceptibility,
- Schottky heat eapacity
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沈阳化工大学材料科学与工程学院沈阳 110142

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Theoretical Research on Optical,Thermal and Magnetic Properties of Ni(pz)4Cl2 Complex

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Theoretical Research on Optical,Thermal and Magnetic Properties of Ni(pz)₄Cl₂ Complex