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Citation: Sun Li-Peng, Ma Ao, Wang Yi-Xuan, Liu Cheng-Bu. Thermodynamic and Kinetic Study of Gas-phase Hydrolysis of CF₃C(O)F to CF₃COOH[J]. Acta Physico-Chimica Sinica, ;1996, 12(04): 361-364. doi: 10.3866/PKU.WHXB19960415 shu

Thermodynamic and Kinetic Study of Gas-phase Hydrolysis of CF₃C(O)F to CF₃COOH

1.
College of Chemistry,Shandong University,Jinan 250100

Received Date: 11 July 1995
Available Online: 15 April 1996

Based on the ab initio calculated results, the thermodynamic functions and kinetic parameters of the gas-phase hydrolysis of CF3C(O)F to CF3COOH have been calculated in the temperature range 200-1500 K with statistical thermodynamic method and Eyring’s transition state theory. The heat capacities of some important species ocurring in the reactions have been calculated and fitted in the formula (a + bT + cT2 + dT3 + eT4).
- Thermodynamics,
- Kinetics,
- CF₃C(O)F,
- Gas-phase hydrolysis
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Thermodynamic and Kinetic Study of Gas-phase Hydrolysis of CF3C(O)F to CF3COOH

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通讯作者: 陈斌, bchen63@163.com

Thermodynamic and Kinetic Study of Gas-phase Hydrolysis of CF₃C(O)F to CF₃COOH