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Citation: Ying Bai-Ning, Wu Guo-Xiang. Charge Transfer Complexation of N-substituted Phenothiazines with DDQ[J]. Acta Physico-Chimica Sinica, ;1995, 11(10): 937-940. doi: 10.3866/PKU.WHXB19951017 shu

Charge Transfer Complexation of N-substituted Phenothiazines with DDQ

1.
Department of Chemistry,Modern Biology Center,Yunnan University,Kunming 650091

Received Date: 26 November 1994
Available Online: 15 October 1995

The charge transfer complexes (CTC) formed from N-substituted phenothiazines with 2,3-dichloro-5,6-dicyanobenzoquione (DDQ ) in 1,2-dichloroethane were studied spectrophotometrically. The CT spectra, ionization potentials of donor and the thermodynamic data (K, △H，△S) of CTC were determined. The results show that the charge donation of N-substituted phenothiazines is fairly strong and depends on the polarity of the substituent.
- Phenothiazines,
- 2,3-dichloro-5,6-decyanobenzoquinone(DDQ),
- Charge transfer complex,
- Ionization potential
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