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Citation: Suo Ji-Shuang, Li Shu-Ben, Wang Hong-Li. Propylene Epoxidation Catalyzed by a Biomimetic System of Cytochrome P450 Supported Metalloporphyrin on SiO₂[J]. Acta Physico-Chimica Sinica, ;1995, 11(02): 101-106. doi: 10.3866/PKU.WHXB19950202 shu

Propylene Epoxidation Catalyzed by a Biomimetic System of Cytochrome P450 Supported Metalloporphyrin on SiO₂

1.
State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000

Received Date: 20 December 1993
Available Online: 15 February 1995

SiO2 supports chemically modified by amine, imidazole were prepared and used to support Mn(TPP)Cl, Mn(TDCPP)Cl for constructing the biomimetic systems of cytochrome P-450 with the single oxygen donor (NaClO) as the terminal oxidant. With such catalytic systems, the propylene could be epoxidized under mild conditions in the aqueous solution of sodium hypochlorite. This fair catalytic behavior compared with that of the unsupported Mn(TPP)Cl was ascribed to the axial ligation of organofunctional group on the SiO2 surface to the central metal of the metalloporphyrins, and the site isolation of active centers which would prevent the formation of μ-oxo-dimers.
- Epoxidation,
- Cytochrome P-450,
- Metalloporphyrin
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Propylene Epoxidation Catalyzed by a Biomimetic System of Cytochrome P450 Supported Metalloporphyrin on SiO2

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Propylene Epoxidation Catalyzed by a Biomimetic System of Cytochrome P450 Supported Metalloporphyrin on SiO₂