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Citation: Wu Bao-Shan, Liu Qi-Wang, Hu Xiang, Su Hai-Quan, Liu Shu-Tang, Jin Xiang-Lin. Syntheses and Crystal Structure of Tetracobalt Carbonyl Clusters Co₄(CO)₈(μ-CO)₂(μ₄-PSR)₂[J]. Acta Physico-Chimica Sinica, ;1994, 10(10): 882-886. doi: 10.3866/PKU.WHXB19941004 shu

Syntheses and Crystal Structure of Tetracobalt Carbonyl Clusters Co₄(CO)₈(μ-CO)₂(μ₄-PSR)₂

1.
National Laboratory for Structural Chemistry of Unstable and Stable Species

Received Date: 27 April 1993
Available Online: 15 October 1994

The title compounds Co4(CO)8(μ-CO)2 (μ4-PSR) [R=-CH3, -C2H5, -C(CH3)3,-(CHa)4CH3] were synthesized by the reaction of Co2(CO)8 with RSPCl2. They were characterized by IR, 1HNMR, elemental analysis. The crystal and molecular structure of Co4(Co)8(μ-CO)2 (μ4-PSC2H5) has been determined by single crystal diffraction method. Crystal data: monoclinic, space group P21 /c, with a=8-445(3), 6=8.562(3), c= 17.125(6)Å, β=104.26 (3)' 9 V=1200.1Å3, Z=2, Dc=1.937gcm-3. Its molecular structure contains an octahedral Co4P2 skeleton which consists of a rectangular four cobalt atoms core and the Co4 core is capped above and below by two quadruply bridging PSR ligands.
- Alkyl sulfide,
- Phosphorus bridged ligand,
- Tetracobalt carbongl cluster,
- Syntheses and crystal structure
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Syntheses and Crystal Structure of Tetracobalt Carbonyl Clusters Co4(CO)8(μ-CO)2(μ4-PSR)2

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Syntheses and Crystal Structure of Tetracobalt Carbonyl Clusters Co₄(CO)₈(μ-CO)₂(μ₄-PSR)₂