引用本文:
吴秉芳, 苏海全, 阎秀英, 胡襄, 刘树堂, 刘启旺, 施剑秋. Rh2(μ-SC6H5)2(CO)4的合成和晶体结构[J]. 物理化学学报,
1994, 10(09): 847-851.
doi:
10.3866/PKU.WHXB19940915
Citation: Wu Bing-Fang, Su Hai-Quan, Yan Xiu-Ying, Hu Xiang, Liu Shu-Tang, Liu Qi-Wang, Shi Jian-Qiu. Synthesis and Crystal Structure of Rh2(μ-SC6H5)2(CO)4[J]. Acta Physico-Chimica Sinica, 1994, 10(09): 847-851. doi: 10.3866/PKU.WHXB19940915
Citation: Wu Bing-Fang, Su Hai-Quan, Yan Xiu-Ying, Hu Xiang, Liu Shu-Tang, Liu Qi-Wang, Shi Jian-Qiu. Synthesis and Crystal Structure of Rh2(μ-SC6H5)2(CO)4[J]. Acta Physico-Chimica Sinica, 1994, 10(09): 847-851. doi: 10.3866/PKU.WHXB19940915
English
Synthesis and Crystal Structure of Rh2(μ-SC6H5)2(CO)4
Abstract:
The title compound was obtained by the reaction of Rh4 (CO)12 with P(SC6H5)3. The crystal structure of the compound has been determined by X-ray diffraction. The crystal system is monoclinic, space group P21/a, a=17.390(8), b=8.983(9),c=24.35(2)Å, β =103.84(4); V=3693(5)Å3, Z=8, DC=1.93g.cm-3. R=0.057, RW=0.064, The intramolecular Rh-Rh distances are 3.090 and 3.078Å respectively.
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Key words:
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Dinuclear rhodium carbonyl
- / Bridging thiolate ligand
- / Crystal structure
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