Citation:
Zhang Wei-De, Zhan Rui-Yun, Ye Xing-Kai, Wu Yue. Preparation of SiO2-ligated Metallo-phthalocyanine(MPc) and it's Role in the Activation of Dioxygen[J]. Acta Physico-Chimica Sinica,
;1994, 10(07): 654-657.
doi:
10.3866/PKU.WHXB19940715
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The metal phthalocyanines (MPc, M=Fe, Co, Cu) were supported on the surface of silica gel by chemical linking. They could not be washed out with organic solvents such as Py. UV-Vis diffuse reflectance spectra indicated that MPc s were supported on silica gel. ESR result showed that the supported CoPc and FePc could react with O_2 to produce O~-_2, but the supported CuPc could not.
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Keywords:
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Metal phthalocyanine
, - Supported; The activation of O2,
- Catalyst,
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