Citation:
Du Hong-Bin, Zhou Qun, Zhou Feng-Qi, Long Wen-Qin. Study on the Synthesis and Structure of Cu-ZSM-5 Type Molecular Sieve[J]. Acta Physico-Chimica Sinica,
;1994, 10(07): 635-638.
doi:
10.3866/PKU.WHXB19940711
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Cu-ZSM-5 type molecular sieves were synthesized hydrothermally in weak acid medium in the presence of F~- ions. The structures of these samples were investigated. Increasing the amount of copper in synthesized samples the unit cell volumes of Cu-ZSM-5 zeolites increase, while the adsorption peaks of Cu-ZSM-5 shift to lower wavenumbers. These facts and the results of the electron probe micrograph and XPS analyese indicate that copper was introduced into the framework of molecular sieve.
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