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Citation: Zhang Bin, Wang Zhe-Min, Liu Shi-Xiong, Huang Jin-Ling. Synthesis and Crystal Structure of a New Metal-rich Layered Ternary Tantalum Telluride TaNi₂Te₂[J]. Acta Physico-Chimica Sinica, ;1994, 10(06): 508-513. doi: 10.3866/PKU.WHXB19940606 shu

Synthesis and Crystal Structure of a New Metal-rich Layered Ternary Tantalum Telluride TaNi₂Te₂

1.
Research Center of Solid State Mterial, Fuzhou University, Fuzhou 350002

Received Date: 3 December 1992
Available Online: 15 June 1994

The title compound has been synthesised by high-temperature solid state reaction. The crystal structure was determined by single crystal X-ray diffraction method. The crystal belongs to orthorhombic system with space group Pnma, Z=4, α=0.6480(1), b=0.35639(6), c=1.6994(4) nm, V=0.3925(1) nm, D_c=9.37 g·cm~(-3), λ(MoK_α)=0.071069 nm, μ(MoK_α)=514.43 cm~(-1) and F(000)=932. The final R is 0.051 for 706 observations. TaNi_2Te_2 is a new metal-rich layered ternary telluride. In the structure two metal sheets are sandwiched below and above by Te layers, leading to planar tri nal coordination for Ta and tri nal pyramidic coordination for Ni by Te atoms. An important structural character of this compound is that all planar five-member TeNi_4 rings are fused together to form an extended structure, and each Ta atom is sandwiched by two TeNi_4 rings.
- Ternary layered telluride,
- Crystal structure,
- Synthesis
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Synthesis and Crystal Structure of a New Metal-rich Layered Ternary Tantalum Telluride TaNi2Te2

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Crystal Structure of a New Metal-rich Layered Ternary Tantalum Telluride TaNi₂Te₂