引用本文:
胡义华, 储焰南, 倪晋智, 李迎春, 李书涛, 曹德兆, 郭敬忠, 刘传朴, 顾月姝. He*(23S)/CO2与CS2反应的化学发光[J]. 物理化学学报,
1994, 10(04): 293-296.
doi:
10.3866/PKU.WHXB19940402
Citation: Hu Yi-Hua, Chu Yan-Nan, Ni Jin-Zhi, Li Ying-Chun, LI Shu-Chao, Cao De-Zhao, Guo Jing-Zhong, Liu Chuan-Pu, Gu Yue-Shu. Chemiluminescence of the Reaction of He*(23S)/CO2 with CS2[J]. Acta Physico-Chimica Sinica, 1994, 10(04): 293-296. doi: 10.3866/PKU.WHXB19940402
Citation: Hu Yi-Hua, Chu Yan-Nan, Ni Jin-Zhi, Li Ying-Chun, LI Shu-Chao, Cao De-Zhao, Guo Jing-Zhong, Liu Chuan-Pu, Gu Yue-Shu. Chemiluminescence of the Reaction of He*(23S)/CO2 with CS2[J]. Acta Physico-Chimica Sinica, 1994, 10(04): 293-296. doi: 10.3866/PKU.WHXB19940402
English
Chemiluminescence of the Reaction of He*(23S)/CO2 with CS2
Abstract:
The reaction of He~*(2~3S)/CO_2 with CS_2 has been studied in discharge fiowing-afterglow apparatus. The emission spectra from exited state products CS~+_2(A)、CS (A,a) have been observed. The formation mechbosm proposed is:
CO~+_2(X)+CS_2→CS~+_2(A)+CO_2
CO(a)+CS_2→OCS(X)+CS(A)
CO(a)+CS_2→OCS(X)+CS(a)
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Key words:
-
Energy transfer
- / Chemiluminescence
- / CS2
- / Charge-transfer reaction
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