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Citation: Zhang Nan, Yu Zhong-De, Feng Wan-Yong, Wu Xiao-Jun, Gao Zhen, Zhu Qi-He, Kong Fan-Ao. The Role of Hydrogen Atoms in the Formation Hydrogenated Carbon Clusters[J]. Acta Physico-Chimica Sinica, ;1994, 10(02): 126-129. doi: 10.3866/PKU.WHXB19940207 shu

The Role of Hydrogen Atoms in the Formation Hydrogenated Carbon Clusters

1.
Laboratory of Molecular Reaction Dynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080

Received Date: 23 July 1992
Available Online: 15 February 1994

Hydrogenated carbon cluster ions (C_nH~+_m) were produced by direct laser ablation of solid aromatic compounds and studied with a time-of flight mass spectrometer. In the low mass region (n=32-56), the hydrogenated carbon clusters were obtained with both even and odd carbon atom numbers, while in the high mass region (n>100), the hydrogenated ones were obtained with only even carbon atom number as well as the pure carbon clusters. A structuxal model combining aromatic group and fullerene-like cage for the low mass region and a model combining snail and cylinder types for the high mass region have been suggested.
- Hydrogenated carbon cluster,
- Laser ablation,
- Time-of-filight mass spectrometer
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