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Citation: Ni Jin-Zhi, Li Shu-Tao, Chu Yan-Nan, Hu Yi-Hua, Cao De-Zhao. Energy Transfer Reaction of Metastable CO(α³П) Molecule with CN Radical[J]. Acta Physico-Chimica Sinica, ;1994, 10(01): 19-21. doi: 10.3866/PKU.WHXB19940106 shu

Energy Transfer Reaction of Metastable CO(α³П) Molecule with CN Radical

1.
Laser Spectroscopy Laboratory, Anhui Institute of Pptics and Fine Mechanics, Academia Sinica, Hefei 230031

Received Date: 14 September 1993
Available Online: 15 January 1994

Energy-transfer reaction from metastable CO(a~3П) molecule to CN radical has been studied in a room-temperature flow reactor. The CN (B-X, △v=0, ±1, ±2) violet emission bands were obtained. The △v=0 sequence of CN(B) were analyzed by computer simulation. The vibrational temperature is 3400 K. By using the reference reaction CO(a)+NO, the formation rate constant of CN(B) has been measured, k_(CN)(B)=1.1×10~(-11) cm~3·molecule~(-1)·s~(-1).
- Metastable CO(a) molecule,
- CN radical,
- Energy transfer
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沈阳化工大学材料科学与工程学院沈阳 110142

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Energy Transfer Reaction of Metastable CO(α3П) Molecule with CN Radical

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Energy Transfer Reaction of Metastable CO(α³П) Molecule with CN Radical