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Citation: Shi Yang, Zhang Nan, Gao Zhen, Zhu Qi-He, Kong Fan-Ao. A Primary Study for the Formation and Photodissociation of Aluminum Sulfide Cluster Ions[J]. Acta Physico-Chimica Sinica, ;1993, 9(03): 299-301. doi: 10.3866/PKU.WHXB19930304 shu

A Primary Study for the Formation and Photodissociation of Aluminum Sulfide Cluster Ions

1.
Institute of Chemistry, Chinese Academia Sinica, The State Key Laboratory of Molecular Reaction Dynamics, Beijing 100080

Received Date: 18 December 1992
Available Online: 15 June 1993

Binary cluster ions consisted of aluminum and sulfur(Al_nS_m~+, n up to 63, m up to 94) are produced by laser ablation of a mixture of aluminum powder and sulfur powder. It was found that the formed cluster ions have a uniform increment of Al_2 S_3 in the composition. The photodissociation of the mass-selected cluster ions also show a simple dissociation channel by loss of(Al_2S_3)_x (x=1 or 3). The structural features of the cluster ions have been discussed.
- Atomic cluster; Photolysis; Structural stability; Laser ablation
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