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Citation: Wang Feng-Yun, Ye Jing-Xian, Chen Min-Sheng. A Calculation of Ion Solvation Enthalpy in Aqueous and Nonaqueous Solutions[J]. Acta Physico-Chimica Sinica, ;1992, 8(05): 673-676. doi: 10.3866/PKU.WHXB19920519 shu

A Calculation of Ion Solvation Enthalpy in Aqueous and Nonaqueous Solutions

1.
Chemistry Department, East China Institute of Technology, Nanjing 210014

Received Date: 15 April 1991
Available Online: 15 October 1992

In the light of the interactions between particles, this paper is a calculation of the standard solvation enthalpies for ions Li~+, Na~+, K~+, Rb~+, Cs~+, Ag~+, Cl~-, Br~- and I~- in solvents as H_2O, MeOH, FA, DMF, DMSO, MeCN, PC and SL. The contributions from the cavity formation process, electrostatic attraction, electrostatic repulsion and those from nonelectrostatic interactions are considered. The accordance between the calculated values and those from literature is od except Li~+.
- Aqueous; Nonaqueous; Solvation enthalpy; Calculation
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