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Citation: Zhang Nan, Wu Ji-Lan. The Inhibition Effects of Tributylphosphate on the Raoiolysis of Cyclohexane[J]. Acta Physico-Chimica Sinica, ;1992, 8(04): 459-463. doi: 10.3866/PKU.WHXB19920407 shu

The Inhibition Effects of Tributylphosphate on the Raoiolysis of Cyclohexane

Zhang Nan ,
Wu Ji-Lan

1.
Department of Technical Physics, Peking University, Beijing 100871

Received Date: 15 March 1991
Available Online: 15 August 1992

The inhibition effects of tributylphosphate on the radiolysis of cyclohexane have been reported. Combintion of the inhibition effects of the radiolytical productshydrogen gas, cyclohexene, bicyclohexyl with results of excitation energy transfer, it was found that the inhibition effects of TBP are performed by two processes: a)excitation energy transfer, b) electron capture. We obtained that the yield of the geminate ion pairs of cyclohexane is 3.8, and the electron capture coefficient of TBP is 6.3 L·mol~(-1).
- Tributylphosphate; Cyclohexane; Radiolysis mechanism; Inhibition effects
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