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Citation: Huang Rong-Bin, Zhang Peng, Zhu Yong-Bao, Zheng Lan-Sun. Mass Spectrometry of Niobium and Sulfur Mixed Cluster Ions Generated in Laser Plasma[J]. Acta Physico-Chimica Sinica, ;1992, 8(01): 8-9. doi: 10.3866/PKU.WHXB19920103 shu

Mass Spectrometry of Niobium and Sulfur Mixed Cluster Ions Generated in Laser Plasma

1.
Department of Chemistry, Xiamen University, Xiamen 361005

Received Date: 4 September 1991
Available Online: 15 February 1992

Cluster ions of niobium and sulfur were generated in laser plasma reactions on a self-built apparatus. Among all Nb_nS_m~+, the cluster cations with the compositions of n<4, m=n+1; n>3, m=n+2 have special high ion intensities in mass spectrum. The cluster anions of high intensities have four more sulfur atoms compared with the relative cations. By analo using to [Mo_3S_4]~(4+) clusters, it is proposed that these cluster ions contain non-planar puckered rings with quasi-aromaticity.
- laser plasma reaction; quasi-aromativitv mixed cluster ions of niobium and sulfur
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