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Citation: Ding Hui-Jun, Tian Bin, Zhao Guo-Xi. Interaction Between Cationic-Antonic and Zwitterionic Surfactant in Mixed Aqueous Solutions[J]. Acta Physico-Chimica Sinica, ;1991, 7(04): 413-419. doi: 10.3866/PKU.WHXB19910408 shu

Interaction Between Cationic-Antonic and Zwitterionic Surfactant in Mixed Aqueous Solutions

1.
Laboratory of Colloid Chemistry, Institute of Physical Chemistry, Peking University, Beijing 100871

Received Date: 27 March 1990
Available Online: 15 August 1991

Cationic-anionic surfactants have a high surface activity. But they are liable to precipitate as the concetration is slightly over cme, so their utilities are restricted. This paper describes their various surface properties and solubility phenomena when zwitterionic surfactant is mixed with them. The results indicate that (1) Owing to solubilization by the zwitterionic surfactant, the solubility of cationic-anionic surfactants is increased. (2) Proper amount of zwitterionic surfactant may keep the surface activity of the cationic-anionic surfactant essentially to be constant. (3) The molecular interaction between cationic-anionic and zwitterionic surfactants is stronger than that between cationic-anionic and nonioic surfactants in both surface layer and micelle; for HC-FC cationic-anionic and zwitterionic systems the saturated adsorption film possibly have a double-or multilayer structure.
- Mixed surfactant; Molecular interaction; Surface activity
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