Citation:
Yang Hua-Quan, Liu Xin, Cai Sheng-Min, Zhou Guo-Ding. A Photoelectrochemical Study of Cyclic Voltammetry of MnO2 Electrode[J]. Acta Physico-Chimica Sinica,
;1991, 7(04): 409-412.
doi:
10.3866/PKU.WHXB19910407
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Electrochemical and photoeletrochemical properties of electrodepositing γ-MnO_2 are studied when it is charged and discharged in 1 mol·L~(-3) KOH using cyclic voltammetry and in-situ photoelectrochemical method. When γ-MnO_2 is reduced,the photocurrent decreases from positive to negative. We concluded that γ-MnO_2 is a n-type semiconductor, but it is p-type doped during the reduction processes.
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