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Citation:
Wu Bing-Liang, Sun Ai-Jun. INVESTIGATION OF VOLTAGE-REGULATED COULOMETRY ON RDE[J]. Acta Physico-Chimica Sinica,
;1990, 6(06): 747-750.
doi:
10.3866/PKU.WHXB19900622
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A voltage-regulated coulometry on RDE is described. It shows that the electric quantity due to the reaction of soluble intermediate Ms, Q_(Ms), is proportional to the inverse square root of the rotation speed, ω~(-1/2). And the slope of the Q_(Ms)-ω~(-1/2) plot is proportional to the surface concentration of the soluble intermediate Ms. However, the qantity Q_(Mad), the electric quantity due to the reaction of adsorbed inter-mediate Mad is independent of the angular velocity of rotation of the electrode.
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