Citation:
Zhu Jian-Jun, Liu Wen-Bin, Lu Jin-Suo, Bai Tong-Chun. The Salt Effect on Phase Transformation in Liquid-Liquid System[J]. Acta Physico-Chimica Sinica,
;1990, 6(02): 246-251.
doi:
10.3866/PKU.WHXB19900222
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The linear equation of salt effect on phase transformation in the mixtures of nonpolar-nonpolar system and nonpolar-polar system can be proved with the aid of perturbation expansion. The cause of linear equation has been discussed from ther-modynamics. By introducing the expanding boundary function, we calculated phase transformation temperatures for a number of systems in which the phenomenon of seperating phase has been observed and compared with experiments.
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