Citation:
Zhou Guo-Zhi, Cai Wen-Juan. Relationships Between the Activities on Boundaries of Two-Phase Region in Ternary Systems and the Dependence of the Relationships on Direction of Tie-Line[J]. Acta Physico-Chimica Sinica,
;1990, 6(02): 169-176.
doi:
10.3866/PKU.WHXB19900209
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Relationships between the activity of a certain component and the product of ac-tivities of three components, Φ, which may be the activity of the compound, on boundaries of two-phase region in ternary systems have been studied. An important formula expressing above mentioned relationships has been derived. It is a common expression which involves various kinds of formulae for two-phase region in ternary systems. At the same time, we analyzed in detail the influence of the direction of tie-line on relationships between the activities. A parameter θ is empolyed in order to overcome the difficulties encountered in integration in the two-phase region. In addition, we consummated Krivsky and Schuhmann's rule on the basis of certain results in the paper.
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