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Citation: Gu Dengping*, Liu Zhaohui. STUDIES ON THE MECHANISM OF ELECTROREDUCTION OF CHLORATE[J]. Acta Physico-Chimica Sinica, ;1989, 5(03): 316-320. doi: 10.3866/PKU.WHXB19890313 shu

STUDIES ON THE MECHANISM OF ELECTROREDUCTION OF CHLORATE

1.
Department of Chemistry; Hebei Teacher's University; Shijiazhuang

Received Date: 14 September 1987
Available Online: 15 June 1989

The electroreduction of chlorate was studied with Mo disk-Pt ring electrode. Two reduction intermediates, ClO_2 and Cl(or Cl_2), have been detected. Some kinetic parameters of the electroreduction of chlorate and reaction orders of reactants were obtained with rotating electrode. According to experimental and calculated results, a mechanism of the electroreduction of chlorate is postulated.
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