Citation:
Lin Hua, Xie Kuangjie, Qian Rulin, Mu Ouorong, Li Changlin*. INFRARED PHOTOCHEMISTRY AND PHOTOPHYSICS OF CF3Br[J]. Acta Physico-Chimica Sinica,
;1988, 4(01): 92-97.
doi:
10.3866/PKU.WHXB19880119
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We present the optothermal and optoacoustic spectra of CF_3Br in TEA CO_2 laser 00°1—02°0 R branch. Three absorption peaks has been observed at R(14) line (1074.6 cm~(-1)), R(18) line (1077.3cm~(-1)), and R(22) line (1079.9cm~(-1)) respectively. The peak at R(22) coincides with the position of P branch of CF_3Br linear IR spectrum, but two peaks at R(14) and R(18) can be interpreted as the hot bands.
We also studied the multiphoton dissociation of CF_3Br and carbon isotope seperation. -
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