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Citation: Qi Dewei. CALCULATION FOR THE SPLITTING OF CRYSTAL FIELD ENERGY LEVELS OF O_h C_2vC₂ GROUP CHAIN IN ZnWO₄ : Ni²⁺ CRYSTAL[J]. Acta Physico-Chimica Sinica, ;1987, 3(02): 209-212. doi: 10.3866/PKU.WHXB19870217 shu

CALCULATION FOR THE SPLITTING OF CRYSTAL FIELD ENERGY LEVELS OF O_h C_2vC₂ GROUP CHAIN IN ZnWO₄ : Ni²⁺ CRYSTAL

Qi Dewei

1.
Chengdu University of Science and Technology

Received Date: 27 November 1985
Available Online: 15 April 1987

An analytic approximation wave function of free ion Ni~(2+) is obtained from Watson′s SCF-3d orbit. Crystal field energy levels in the ZnWO_4 : Ni~(2+) crystal are then calculated with this wave function using ligand theory. The calculation are based on real C_2 symmetry of the crystal and according to the descending symmetry devided in two steps. O_h C_(2v) and C_(2v) C_2. Sometimes it is difficult to determine the numerous parameters from spectral data in case of lower symmetry crystal. We try to overcome this difficulty. The theoretical calculations are in od agreement with the experimental results.
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CALCULATION FOR THE SPLITTING OF CRYSTAL FIELD ENERGY LEVELS OF Oh C2v C2 GROUP CHAIN IN ZnWO4 : Ni2+ CRYSTAL

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通讯作者: 陈斌, bchen63@163.com

CALCULATION FOR THE SPLITTING OF CRYSTAL FIELD ENERGY LEVELS OF O_h C_2vC₂ GROUP CHAIN IN ZnWO₄ : Ni²⁺ CRYSTAL