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Citation: Tian Zhaown. THEORETICAL ANALYSIS ON THE PHOTOELECTRIC CONVERSION OF POLYMER SEMICONDUCTOR[J]. Acta Physico-Chimica Sinica, ;1985, 1(01): 82-88. doi: 10.3866/PKU.WHXB19850111 shu

THEORETICAL ANALYSIS ON THE PHOTOELECTRIC CONVERSION OF POLYMER SEMICONDUCTOR

Tian Zhaown

1.
Institute of Physical Chemistry; Xiamen University; Xiamen; Fujian; China

Received Date: 26 June 1984
Available Online: 15 February 1985

Sunlight may be converted into electrical or chemical energy by semiconductors composed of suitably doped polymers (e.g. polyaeetylene). The mobility of the dopant in the polymer is significant and the concentration of dopant is not uniform in the semiconductor polymer because of the electric field in the space-charge region. The theoretical treatment for traditional semiconductor, even the depletion layer approximation cermet be applied to this case. It is interesting to study quantitatively the distributions of concenrations of dopant and carriers as well as the electric potential and field. In order to search for polymer semiconductor material as photoelectrode of high performance, it is necessary to study quantitative relationships between the conversion efficiency and various parameters of the semiconductor bulk properties.
For the steady state of a planar n-type semiconductor illuminated by monochromatic light, the following six simultaneous differential equations can be formulated:
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THEORETICAL ANALYSIS ON THE PHOTOELECTRIC CONVERSION OF POLYMER SEMICONDUCTOR

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com