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Citation: Jiaxi Xu, Yuan Ma. Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide[J]. University Chemistry, ;2024, 39(11): 374-377. doi: 10.3866/PKU.DXHX202402049 shu

Influence of Hyperconjugation on the Stability and Stable Conformation of Ethane, Hydrazine, and Hydrogen Peroxide

Jiaxi Xu ¹ ,
Yuan Ma ²

1.
College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, China;
2.
Department of Chemistry, Tsinghua University, Beijing 100084, China

Received Date: 23 February 2024
Revised Date: 3 April 2024

Ethane, hydrazine, and hydrogen peroxide are three structurally similar substances composed of the elements from the same period with hydrogen, respectively. However, their stability significantly decreases in a sequential manner, and their stable conformations are also dissimilar. These differences have not been explained adequately in the current textbooks. This article provides a possible explanation for the variation in stability among these substances by analyzing their n-σ^* hyperconjugation. Additionally, it elucidates the absence of anti-conformation in hydrazine and hydrogen peroxide. The hyperconjugation theory is extended to illustrate and to discuss stability and stable conformation of inorganic compounds.
- Ethane,
- Hydrazine,
- Hydrogen peroxide,
- Stability,
- Conformation,
- Hyperconjugation
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