Citation: Wangze Song, Wenfeng Jiang. Research Progress in Achmatowicz Rearrangement Reaction[J]. University Chemistry, ;2023, 38(1): 111-118. doi: 10.3866/PKU.DXHX202203077 shu

Research Progress in Achmatowicz Rearrangement Reaction

Wangze Song ,
Wenfeng Jiang ^,

School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning Province, China

Corresponding author: Wenfeng Jiang, jiangwf@dlut.edu.cn
Received Date: 28 March 2022

The Achmatowicz rearrangement reaction is an important organic reaction that is based on a unique oxidative rearrangement mechanism. The reaction is widely used in organic synthesis, medicinal chemistry, and other fields, and its products are important fine chemicals that are widely used in the total synthesis of complex natural products. This article reviews the mechanism underlying the Achmatowicz rearrangement reaction and its research progress, including bromine and peroxidation and participation of high valence metal oxidants, photo promotion, and enzyme-catalyzed Achmatowicz rearrangement reaction. Moreover, the future development and opportunities in this field are discussed.
- Achmatowicz rearrangement reaction,
- Oxidative rearrangement reaction,
- Research progress
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