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Citation: Laiying Zhang, Wei Kang, Haojin Xu, Haobo Zhao, Qiangwei Wang, Weitai Wu. e-ATRP水相制备温度响应高分子微凝胶——有关高分子微凝胶的新实验设计与实践[J]. University Chemistry, ;2022, 37(2): 210502. doi: 10.3866/PKU.DXHX202105025 shu

e-ATRP水相制备温度响应高分子微凝胶——有关高分子微凝胶的新实验设计与实践

College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, China

Received Date: 10 May 2021

介绍一个涵盖高分子化学、电合成与仪器分析等领域的基础实验。本实验基于e-ATRP原理，采用简便易得的电化学反应装置，在水溶液中微量合成温度响应高分子微凝胶，并使用紫外-可见分光光度计和动态光散射仪探究微凝胶的温度响应特性。本实验取材于广受关注且已有较多验证的研究前沿成果，允许拓展合成其他高分子，也可进一步尝试各种电化学技术，简便易行、绿色环保，有助于培养学生的学科交叉融合思维和环保意识，锻炼创新实践能力。
- e-ATRP,
- Temperature-responsive,
- Polymeric microgels,
- Aqueous system
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
  Wang, J. S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614.
7. [7]
  Matyjaszewski, K.; Teodorescu, M.; Miller, P. J.; Peterson, M. L. J. Polym. Sci. Pol. Chem. 2000, 38, 2440.
8. [8]
  Sanson, N.; Rieger, J. Polym. Chem. 2010, 1, 965.
9. [9]
  Magenau, A. J. D.; Strandwitz, N. C.; Gennaro, A.; Matyjaszewski, K. Science 2011, 332, 81.
10. [10]
  Bortolamei, N.; Isse, A. A.; Magenau, A. J. D.; Gennaro, A.; Matyjaszewski, K. Angew. Chem. Int. Edit. 2011, 50, 11391.
11. [11]
1. [1]
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2. [2]
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3. [3]
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5. [5]
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9. [9]
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