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Citation: Xiaoqing Ouyang, Chunyan Zhang, Zhenling Xu, Rui Pan, Yinyun Lü, Chanzi Ruan, Yuhua Weng, Zhiqiang Dong, Yanping Ren. trans/cis-[Co (en)₂Cl₂]Cl配合物的制备及其水解反应动力学常数测定——面向大一学生的基础型综合化学实验[J]. University Chemistry, ;2021, 36(4): 200506. doi: 10.3866/PKU.DXHX202005062 shu

trans/cis-[Co (en)₂Cl₂]Cl配合物的制备及其水解反应动力学常数测定——面向大一学生的基础型综合化学实验

National Demonstration Center for Experimental Chemistry Education(Xiamen University), College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, China

Corresponding author: Yanping Ren, ypren@xmu.edu.cn
Received Date: 22 May 2020

为大一学生推荐一个基础型综合化学实验，即厦门大学为“化学拔尖计划”一年级学生个性化培养“量身定制”并经10年教学实践而逐步改进完善的实验项目——trans/cis-[Co（en）₂Cl₂]Cl配合物的制备及其水解反应动力学常数测定。该实验项目涵盖了配合物顺-反异构体、晶体场分裂能、配合物的水解反应动力学等基础理论知识，以及顺-反异构体配合物的制备、光谱鉴定及不同介质中水解反应动力学研究等实验操作技能。通过系统的实验，使学生深入了解顺-反异构体配合物的制备、分离和鉴定方法以及配合物水解反应动力学研究的思路和方法等，有助于学生对结构决定性质的直观认识和深刻理解，有助于加强学生对理论与实验的深度融合以及对学生的分析、判断和批判性思维能力的培养。
- Basic comprehensive experiment,
- Cobalt(III) complexes,
- cis/trans isomers,
- Preparation and identification,
- Kinetics of hydrolysis reaction
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trans/cis-[Co (en)2Cl2]Cl配合物的制备及其水解反应动力学常数测定——面向大一学生的基础型综合化学实验

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trans/cis-[Co (en)₂Cl₂]Cl配合物的制备及其水解反应动力学常数测定——面向大一学生的基础型综合化学实验