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Citation: XU Wei, XU Jia-Xi. Molecular Orbital Description on Several Classical Organic Reactions[J]. University Chemistry, ;2016, 31(8): 60-65. doi: 10.3866/PKU.DXHX201510006 shu

Molecular Orbital Description on Several Classical Organic Reactions

XU Wei ,
XU Jia-Xi

Department of Organic Chemistry, Faculty of Science, Beijing University of Chemical Technology, Beijing 100029, P. R. China

It is very important to describe organic reaction processes with molecular orbitals, especially frontier orbitals, for correct and completely understanding of organic reaction mechanisms. Molecular orbital description can provide useful information on selectivity and stereochemistry of organic reactions. Molecular orbital descriptions on several classic organic reactions, including aliphatic and aromatic nucleophilic substitutions, electrophilic aromatic substitution, addition and elimination, are discussed.
- Organic reaction,
- Molecular orbital,
- Nucleophilic substitution,
- Addition,
- Elimination
1. [1]
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3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
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