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Citation: ZHANG Guangrui, ZHANG Wenfen, GUO Yun, ZHANG Suning, ZHANG Shusheng. Application of calixarene stationary phases to liquid chromatography[J]. Chinese Journal of Chromatography, ;2020, 38(4): 392-398. doi: 10.3724/SP.J.1123.2019.08027 shu

Application of calixarene stationary phases to liquid chromatography

1.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China;
2.
The Center of Advanced Analysis and Gene Sequencing, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: ZHANG Wenfen, zhangwenfen1988@126.com
Received Date: 26 August 2019

Fund Project: National Natural Science Foundation of China (Nos. 21775140,21974124)

Calixarenes are cyclic oligomers composed of phenol units linked by methylene bridges. Because of their unique host-guest recognition ability, calixarenes are considered to be the main representatives of the third generation of supramolecular chemistry after crown ethers and cyclodextrins. Calixarenes are widely used in ion channel as well as in organic catalytic reactions, transmembrane transport, purification, and chromatographic separation. A variety of versatile calixarene derivatives with different recognition ability and special selectivity were prepared by modifying different types of compounds due to calixarenes are easy to derivatize. These derivatives were successfully applied to different chromatographic modes to achieve the separation and analysis of complex samples. This review summarizes the recent advances in stationary phases based on calixarenes and their derivatives for liquid chromatography The prospects of calixarenes in chromatographic separation science are also presented.
- calixarenes,
- heteracalixaromatics,
- stationary phase,
- review
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