Citation: CAI Lipeng, LÜ Xiaofei, ZHANG Bei, LI Xiaoying, ZHAO Xiaofu. Simultaneous determination of 12 preservatives and antioxidants in fruit and vegetable detergents by gas chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, ;2019, 37(1): 111-115. doi: 10.3724/SP.J.1123.2018.08009 shu

Simultaneous determination of 12 preservatives and antioxidants in fruit and vegetable detergents by gas chromatography-mass spectrometry

Hebei Provincial Research Institute of Environmental Protection Products Quality Supervision and Inspection, China National Center for Quality Supervision and Test of Environmental Protection Products, Shijiazhuang 050091, China

Received Date: 6 August 2018

Fund Project: Science and Technology Plan of Hebei Provincial Administration of Quality and Technical Supervision (No. 2016ZD07).

A method was established for the simultaneous determination of 12 preservatives and antioxidants in fruit and vegetable detergents by gas chromatography-mass spectrometry (GC-MS). First, ethanol was added to remove the water in the sample by rotary evaporation and was extracted with acetonitrile in saturated n-hexane. Finally, the residual surfactant in the sample solution was removed with a saturated sodium chloride solution. The purified sample solution was concentrated and metered volume by acetonitrile. The preservatives and antioxidants were separated on a HP-5MS UI capillary column (30 m×0.25 mm×0.25 μm), and detected in the selective ion monitoring (SIM) mode. The method had a good linearity in the range of 0.1-10 mg/L with correlation coefficients (r²)>0.999, and the limits of detection (LODs) and limits of quantification (LOQs) were in the ranges of 0.010-0.030 mg/kg and 0.030-0.090 mg/kg, respectively. The recoveries of the 12 preservatives and antioxidants at three spiked levels (0.2, 2.0 and 10 mg/kg) were 68.3%-115.3% with the relative standard deviations (RSDs) of 3.1%-11.3%. (n=7) The method is sensitive and accurate, and can be suitable for the determination of preservatives and antioxidants in fruit and vegetable detergents.
- gas chromatography-mass spectrometry (GC-MS),
- preservatives,
- antioxidants,
- fruit and vegetable detergents
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
1. [1]
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