Citation: PENG Xiaojun, QIN Han, WEN Qijing, LIANG Weihua, LIANG Youzhen. Application of homemade double solid phase extraction column for determination of 11 organophosphorus pesticides in Xinhui dried orange peel and its products[J]. Chinese Journal of Chromatography, ;2016, 34(8): 817-822. doi: 10.3724/SP.J.1123.2016.04002 shu

Application of homemade double solid phase extraction column for determination of 11 organophosphorus pesticides in Xinhui dried orange peel and its products

1.
Xinhui Entry-Exit Inspection and Quarantine Bureau, Jiangmen 529100, China

Corresponding author: PENG Xiaojun,
Received Date: 4 April 2016

Fund Project:

By packing N-propylethylenediamine (PSA) and multi-walled carbon nanotubes (MWNTs) separately, a homemade double solid phase extraction purification column was made. A gas chromatographic method was developed for the simultaneous determination of 11 kinds of organophosphorus pesticides, including dichlorovos, methamidophos, acephate, phorate, omethoate, dimethoate, chlorpyrifos, malathion, parathion-ethyl, quinalphos and ethion in Xinhui dried orange peel and its products. The samples were centrifuged after extracted by ethyl acetate, and then cleaned up with a homemade double PSA/MWNTs solid phase extraction column. The separation of target compounds was performed on an Agilent RTS-1701 capillary column with temperature programmed within 25 min, then determined by a flame photometric detector and quantified by using external standard method. The factors affecting the determination, such as packing type, amount of packing, elution mode, extraction solution and ultrasonic time, were investigated. Under the optimized experimental conditions, the novel method showed a good linearity in the range of 0.020-1.0 mg/L with correlation coefficients of 0.9990-0.9998, the limits of detection were 3.5-9.6 μ g/kg for the pesticides. The new method was successfully applied to the analyses of organophosphorus pesticides in Xinhui dried orange peel and its products. The recoveries spiked with organophosphorus pesticides standards at three concentration levels of 10, 25 and 100 μ g/kg in samples were 50.8%-109% with relative standard deviations of 2.7%-8.5%. The established method is accurate, sensitive, simple and fast. The detection limits of the method meet the limited requirements of organophosphorus pesticide residues. The homemade column is cost saving and worthy of popularization and application. The study provides a useful method for the analysis of trace substance.
- homemade double solid phase extraction column,
- gas chromatography (GC),
- organophosphorus pesticides (OPPs),
- Xinhui dried orange peel
1. [1]
  [1] Liu Y, Tang Y F, Song J F, et al. Chinese Journal of Chromatography, 2014, 32(2): 139 刘永, 唐英斐, 宋金凤, 等. 色谱, 2014, 32(2): 139
2. [2]
  [2] Martha P, Garcia D L, Maria L, et al. Food Chem, 2009, 114(4): 1510
3. [3]
  [3] Zhang C X, Hou M, Bao H Y, et al. Journal of Qinghai Normal University (Natural Science), 2012(1): 54 张呈祥, 侯明, 鲍海咏, 等. 青海师范大学学报(自然科学版), 2012(1): 54
4. [4]
  [4] Hu Y Q, Xi C X, Cao S R, et al. Chinese Journal of Chromatography, 2014, 32(7): 784 胡业琴, 郗存显, 曹淑瑞, 等. 色谱, 2014, 32(7): 784
5. [5]
  [5] Zhao W J, Sun X K, Deng X N, et al. Food Chem, 2011, 127(2): 683
6. [6]
  [6] Huang Q, He M, Chen B B, et al. Chinese Journal of Chromatography, 2014, 32(10): 1131 黄倩, 何蔓, 陈贝贝, 等. 色谱, 2014, 32(10): 1131
7. [7]
  [7] Cheng Z, Zhang R, Liu W H, et al. Chinese Journal of Chromatography, 2014, 32(1): 57 程志, 张蓉, 刘韦华, 等. 色谱, 2014, 32(1): 57
8. [8]
  [8] Wu L J, Song Y, Hu M Z, et al. Talanta, 2015, 134: 366
9. [9]
  [9] Wang Z M, Zhao X, Xu X, et al. Anal Chim Acta, 2013, 760: 60
10. [10]
  [10] Sanagi M M, Salleh S, Ibrahim W A W, et al. J Food Compos Anal, 2013, 32(2): 155
11. [11]
  [11] Zheng X Y, He L J, Duan Y J, et al. J Chromatogr A, 2014, 1358: 39
12. [12]
  [12] Xu Z L, Sun W J, Yang J Y, et al. J Agric Food Chem, 2012, 60(9): 2069
13. [13]
  [13] Prince A E, Fan T S, Skoczenski B A, et al. Anal Chim Acta, 2001, 444: 37
14. [14]
  [14] GB/T 5009.20-2003
15. [15]
  [15] GB/T 5009.145-2003
16. [16]
  [16] GB/T 14553-2003
17. [17]
  [17] Liu J, Rinzler A G, Dai H J, et a1. Science, 1998, 280: 1253
1. [1]
  Qilong Fang , Yiqi Li , Jiangyihui Sheng , Quan Yuan , Jie Tan . Magical Pesticide Residue Detection Test Strips: Aptamer-based Lateral Flow Test Strips for Organophosphorus Pesticide Detection. University Chemistry, 2024, 39(5): 80-89. doi: 10.3866/PKU.DXHX202310004
2. [2]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
3. [3]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
4. [4]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
5. [5]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
6. [6]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
7. [7]
  Qianlang Wang , Jijun Sun , Qian Chen , Quanqin Zhao , Baojuan Xi . The Appeal of Organophosphorus Compounds: Clearing Their Name. University Chemistry, 2025, 40(4): 299-306. doi: 10.12461/PKU.DXHX202405205
8. [8]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
9. [9]
  Mengzhen JIANG , Qian WANG , Junfeng BAI . Research progress on low-cost ligand-based metal-organic frameworks for carbon dioxide capture from industrial flue gas. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 1-13. doi: 10.11862/CJIC.20240355
10. [10]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
11. [11]
  Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
12. [12]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
13. [13]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
14. [14]
  Haiyang Zhang , Yanzhao Dong , Haojie Li , Ruili Guo , Zhicheng Zhang , Jiangjiexing Wu . Exploring the Integration of Chemical Engineering Principle Experiment with Cutting-Edge Research Achievements. University Chemistry, 2024, 39(10): 308-313. doi: 10.12461/PKU.DXHX202405035
15. [15]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
16. [16]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
17. [17]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1825-1839. doi: 10.11862/CJIC.20240225
18. [18]
  Feng Sha , Xinyan Wu , Ping Hu , Wenqing Zhang , Xiaoyang Luan , Yunfei Ma . Design of Course Ideology and Politics for the Comprehensive Organic Synthesis Experiment of Benzocaine. University Chemistry, 2024, 39(2): 110-115. doi: 10.3866/PKU.DXHX202307082
19. [19]
  Xinyu Zhu , Meili Pang . Application of Functional Group Addition Strategy in Organic Synthesis. University Chemistry, 2024, 39(3): 218-230. doi: 10.3866/PKU.DXHX202308106
20. [20]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(726)
HTML views(194)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142