Citation: LI Jian, XU Lanying, XUE Shuwen, XU Li. Determination of ultraviolet filters in environmental aqueous samples by dispersive liquid-liquid microextraction with online derivatization-gas chromatography-mass spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(10): 1138-1143. doi: 10.3724/SP.J.1123.2014.05040 shu

Determination of ultraviolet filters in environmental aqueous samples by dispersive liquid-liquid microextraction with online derivatization-gas chromatography-mass spectrometry

LI Jian ^1,2 ,
XU Lanying ¹ ,
XUE Shuwen ² ,
XU Li ^2,,

1.
1. Hubei Key Laboratory of Economic Forest Germplasm Improvement and Resources Comprehensive Utilization, Huanggang Normal University, Huanggang 438000, China;

Corresponding author: XU Li,
Received Date: 30 May 2014

Fund Project: 教育部2012年度“新世纪优秀人才支持计划”项目(NCET-12-0213) (NCET-12-0213)黄冈师范学院经济林木种质改良与资源综合利用湖北省重点实验室开放基金项目(2013000903). (2013000903)

A method of dispersive liquid-liquid microextraction (DLLME) combined with online derivatization-gas chromatography-mass spectrometry (GC-MS) was developed for the determination of benzophenone-type ultraviolet (UV) filers (BPs) in environmental aqueous samples. It is found that the online derivatization was superior to the off-line derivatization with its simplicity, high reaction efficiency and less consumption of potential poisonous reagents. The influential factors for online derivatization, including the temperature of the injection port, the splitless time, the proportion of derivatization reagent and sample solution, were initially optimized. In addition, the influential factors for DLLME, including the type of the extractant and dispersing solvent, the proportion of the extractant and the dispersing solvent, the volume of sample solution, the pH and the salt concentration of the sample solution were individually optimized in detail. Under the optimized derivatization and DLLME conditions, the limits of detection for the six BPs, benzophenone, 2,4-dihydroxybenzophenone, oxybenzone, 4-hydroxybenzophenone, octabenzone and 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, ranged from 0.011 to 0.15 μg/L. The intra-day and inter-day relative standard deviations varied from 0.7% to 16.6%. The method was applied to the analysis of lake and river water with good recoveries. It is cost effective, reliable, easy to operate, environment-friendly and promising in the real applications.
1. [1]
  [1] Guo Z Y, Lei J H, Ding Z M. Plastic Additives (郭振宇, 雷建华, 丁著明. 塑料助剂), 2007(5): 8
2. [2]
  [2] Díaz-Cruz M S, Llorca M, Barceló D. TrAC-Trend Anal Chem, 2008, 27(10): 873
3. [3]
  [3] Kunisue T, Wu Q, Tanabe S, et al. Anal Methods, 2010, 2(6): 707
4. [4]
  [4] Takatori S, Kitagawa Y, Oda H, et al. J Health Sci, 2003, 49(2): 91
5. [5]
  [5] Schlumpf M, Cotton B, Conscience M, et al. Environ Health Perspect, 2001, 109(3): 239
6. [6]
  [6] Mao X Q, Bian H T, Qu B C. Chinese Journal of Chromatography (毛希琴, 边海涛, 曲宝成. 色谱), 2013, 31(8): 775
7. [7]
  [7] Lin W X, Sun X Q, Ma J. Chinese Journal of Chromatography (林维宣, 孙兴权, 马杰. 色谱), 2013, 31(5): 410
8. [8]
  [8] Zhang Y F, Lee H K. J Chromatogr A, 2013, 1271: 56
9. [9]
  [9] Vidal L, Chisvert A, Canals A, et al. Talanta, 2010, 81: 549
10. [10]
  [10] Ge D, Lee H K. J Chromatogr A, 2012, 1251: 27
11. [11]
  [11] Zhang P P, Shi Z G, Yu Q W, et al. Talanta, 2011, 83: 1711
12. [12]
  [12] Ding Y R, Huang Y, Zhao T T, et al. Chinese Journal of Chromatography (丁怡然, 黄云, 赵婷婷, 等. 色谱), 2014, 32(6): 629
13. [13]
  [13] Kawaguchi M, Ito R, Honda H, et al. J Chromatogr A, 2008, 1200: 260
14. [14]
  [14] Wang L L, Jia Y L, Pan Z F, et al. Chinese Journal of Chromatography (王丽丽, 贾以律, 潘再法, 等. 色谱), 2008, 26(6): 731
15. [15]
  [15] Wang Q, Ma L Y, Yin C R, et al. J Chromatogr A, 2013, 1296: 25
16. [16]
  [16] Ye L, Zhang C, Xu L. Journal of Analytical Science (叶蕾, 张聪, 徐丽. 分析科学学报), 2011, 27(5): 665
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