Citation: QIAN Feizhong, ZHU Libo, XU Nengbin, FENG Jiayong, HONG Zhengfang, XU Lihong, CHEN Zhongquan, WANG Shengle. Analysis of picric acid and picramic acid in water samples by ultra performance hydrophilic interaction chromatography-tandem mass spectrometry[J]. Chinese Journal of Chromatography, ;2014, 32(5): 535-538. doi: 10.3724/SP.J.1123.2013.11037 shu

Analysis of picric acid and picramic acid in water samples by ultra performance hydrophilic interaction chromatography-tandem mass spectrometry

1.
1. Ningbo Environmental Monitoring Center, Ningbo 315012, China;

Corresponding author: FENG Jiayong,
Received Date: 19 November 2013
Available Online: 19 February 2014
Fund Project: 国家水体污染控制与治理重大专项(2009ZX07527-005) (2009ZX07527-005)宁波市自然科学基金项目(2011A610087,201201A6107004). (2011A610087,201201A6107004)

An ultra performance liquid chromatography/tandem mass spectrometry (UPLC-MS/MS) method was developed for the determination of picric acid and its reductive transformation product picramic acid in aqueous samples. A hydrophilic interaction liquid chromatography (HILIC) column (Acquity UPLC BEH HILIC; 100 mm×2.1 mm, 1.7 μm) was used for the separation. Surface water samples could be injected into the UPLC system just after being filtered through a 0.2 μm membrane. The satisfactory recoveries of picric acid and picramic acid were in the range of 89%-107%. Waste water samples were purified by solid phase extraction (SPE), and then were analyzed. The recoveries of picric acid and picramic acid in waste water were 72%-101%. The reproducibility of the method was good with the RSDs of 4.9%-14.7%. The limits of detection (LODs) of picric acid and picramic acid were 0.1 μg/L and 0.3 μg/L, respectively. This proposed method is rapid, highly specific and suitable for the confirmation and quantitative determination of picric acid and picramic acid in surface water and waste water.
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