Citation: HE Shiwei, HUANG Zhongping, ZHU Yan. Recent advances in preparation of novel chromatographic stationary phases with carbon nanotubes[J]. Chinese Journal of Chromatography, ;2013, 31(12): 1146-1153. doi: 10.3724/SP.J.1123.2013.08043 shu

Recent advances in preparation of novel chromatographic stationary phases with carbon nanotubes

1.
1. Institute of Scientific and Technical Information of Zhejiang Province, Hangzhou 310006, China;

Corresponding author: HUANG Zhongping,
Received Date: 26 August 2013
Available Online: 1 November 2013
Fund Project:

Carbon nanotubes (CNTs) as a new functional material have attracted the interest of scientists and engineers in analytical chemistry, due to their excellent physical, chemical and mechanical properties. The preparation of gas chromatographic stationary phases with CNTs has been performed by packing method or in situ catalytic chemical vapor deposition. The deposition of CNTs on a chromatographic solid matrix (e. g. silica micro-particles or organic polymer microspheres) was carried out to generate a packing material for high performance liquid chromatography. Capillary monolithic columns for liquid chromatography were also prepared by embedding CNTs in polymer monolithic columns. Columns with CNTs have the unique advantages in the separation of aromatic compounds for the π electron system of CNTs. Herein, the recent applications of CNTs in the preparation of chromatographic stationary phases are reviewed, including gas chromatography and liquid chromatography. The future developments in this field are also prospected.
- carbon nanotubes,
- chromatographic stationary phases,
- gas chromatography (GC),
- liquid chromatography (LC),
- review
1. [1]
  [1] Iijima S. Nature, 1991, 354(7): 56
2. [2]
  [2] Poole C P, Owens F J. Introduction to Nanotechnology. Hoboken, NJ, USA: John Wiley and Sons Inc, 2003
3. [3]
  [3] Connell M O. Carbon Nanotubes: Properties and Applications. Boca Raton, FL, USA: CRC, 2006
4. [4]
  [4] Gogotsi Y. Carbon Nanomaterials. Boca Raton, FL, USA: CRC, 2006
5. [5]
  [5] Yang B X, Pramoda K P, Xu G Q, et al. Adv Funct Mater, 2007, 17(13): 2062
6. [6]
  [6] Piran M, Kotlyar V, Medina D D, et al. J Mater Chem, 2009, 19(5): 631
7. [7]
  [7] Gopalan A I, Lee K P, Ragupathy D. Biosens Bioelectron, 2009, 24(7): 2211
8. [8]
  [8] Zhu X Y, Lee S M, Lee Y H, et al. Phys Rev Lett, 2000, 85(13): 2757
9. [9]
  [9] Fu S L, Ding L, Zhu S H, et al. Chinese Journal of Chromatography (付善良, 丁利, 朱绍华, 等. 色谱), 2011, 29(8): 737
10. [10]
  [10] Wu X H, Ding L, Li Z H, et al. Chinese Journal of Chromatography (吴新华, 丁利, 李忠海, 等. 色谱), 2010, 28(11): 1094
11. [11]
  [11] Zhao H X, Jia Y X, Ding M Y, et al. Chinese Journal of Chromatography (赵海香, 贾艳霞, 丁明玉, 等. 色谱), 2011, 29(5): 443
12. [12]
  [12] Peng X J, Pang J S, Deng A H, et al. Chinese Journal of Chromatography (彭晓俊, 庞晋山, 邓爱华, 等. 色谱), 2012, 30(9): 966
13. [13]
  [13] Wu C X, Wang C, Wang Z. Chinese Journal of Chromatography (武春霞, 王春, 王志. 色谱), 2011, 29(1): 6
14. [14]
  [14] Mittermuller M, Volmer D A. Analyst, 2012, 137(14): 3195
15. [15]
  [15] Zhang Z X, Wang Z Y, Liao Y P, et al. J Sep Sci, 2006, 29(12): 1872
16. [16]
  [16] Chen A, Holt-Hindle P. Chem Rev, 2010, 110(6): 3767
17. [17]
  [17] Tasis D, Tagmatarchis N, Bianco A, et al. Chem Rev, 2006, 106(3): 1105
18. [18]
  [18] Li Q L, Yuan D X. J Chromatogr A, 2003, 1003(1/2): 203
19. [19]
  [19] Li Q L, Yuan D X. Acta Chimica Sinica (李权龙, 袁东星. 化学学报), 2002, 60(10): 1876
20. [20]
  [20] Speltini A, Merli D, Quartarone E, et al. J Chromatogr A, 2010, 1217(17): 2918
21. [21]
  [21] Merli D, Speltini A, Ravelli D, et al. J Chromatogr A, 2010, 1217(46): 7275
22. [22]
  [22] Speltini A, Merli D, Dondi D, et al. Anal Bioanal Chem, 2012, 403(4): 1157
23. [23]
  [23] Lin Y, Taylor S, Li H, et al. J Mater Chem, 2004, 14(4): 527
24. [24]
  [24] Menna E, Negra F D, Prato M, et al. Carbon, 2006, 44(8): 1581
25. [25]
  [25] Chang Y X, Zhou L L, Li G X, et al. J Liq Chromatogr R T, 2007, 30(19): 2953
26. [26]
  [26] Kwon S H, Park J H. J Sep Sci, 2006, 29(7): 945
27. [27]
  [27] Andre C, Gharbi T, Guillaume Y C. J Sep Sci, 2009, 32(10): 1757
28. [28]
  [28] Andre C, Aljhani R, Gharbi T, et al. J Sep Sci, 2011, 34(11): 1221
29. [29]
  [29] Liang X J, Liu S J, Liu H M, et al. J Sep Sci, 2010, 33(21): 3304
30. [30]
  [30] Zhong Y Y, Zhou W F, Zhang P M, et al. Talanta, 2010, 82(4): 1439
31. [31]
  [31] Zakaria P, Hutchinson J P, Avdalovic N, et al. Anal Chem, 2005, 77(2): 417
32. [32]
  [32] Hilder E F, Svec F, Frechet J M J. J Chromatogr A, 2004, 1053(1/2): 101
33. [33]
  [33] Slingsby R W, Pohl C A. J Chromatogr, 1988, 458(1): 241
34. [34]
  [34] Huang Z P, Wu H W, Wang F L, et al. J Chromatogr A, 2013, 1294(1): 152
35. [35]
  [35] Huang Z P, Xi L L, Subhani Q, et al. Carbon, 2013, 62(1): 127
36. [36]
  [36] Saridara C, Mitra S. Anal Chem, 2005, 77(21): 7094
37. [37]
  [37] Karwa M, Mitra S. Anal Chem, 2006, 78(6): 2064
38. [38]
  [38] Hussain C M, Saridara C, Mitra S. Anal Chem, 2010, 82(12): 5184
39. [39]
  [39] Hussain C M, Saridara C, Mitra S. RSC Adv, 2011, 1(4): 685
40. [40]
  [40] Yuan L M, Ren C X, Li L, et al. Anal Chem, 2006, 78(18): 6384
41. [41]
  [41] Ren C X, Ai P, Yuan L M. Chinese Journal of Analysis Laboratory (任朝兴, 艾萍, 袁黎明. 分析试验室), 2008, 27(7): 23
42. [42]
  [42] Zhao L, Ai P, Xiong W W, et al. Chinese Journal of Analysis Laboratory (赵丽, 艾萍, 熊维伟, 等. 分析试验室), 2009, 28(9): 85
43. [43]
  [43] Zhao L, Ai P, Duan A H, et al. Anal Bioanal Chem, 2011, 399(1): 143
44. [44]
  [44] Sun C, Zheng Y J, Tian J Z. Journal of Science of Teachers' College and University (孙澈, 郑永杰, 田景芝. 高师理科学刊), 2013, 33(2): 57
45. [45]
  [45] Wang Q, Svec F, Frechet J M J. Anal Chem, 1993, 65(17): 2243
46. [46]
  [46] Wang Q, Svec F, Frechet J M J. J Chromatogr A, 1994, 669(1/2): 230
47. [47]
  [47] Li Y, Chen Y, Xiang R, et al. Anal Chem, 2005, 77(5): 1398
48. [48]
  [48] Chambers S D, Svec F, Frechet J M J. J Chromatogr A, 2011, 1218(18): 2546
49. [49]
  [49] Ren H B, Liu R M. Chinese Journal of Analysis Laboratory (任呼博, 柳仁民. 分析试验室), 2009, 28(12): 1
50. [50]
  [50] Andre C, Lenancker G, Guillaume Y C. Talanta, 2012, 99(1): 580
51. [51]
  [51] Aqel A, Yusuf K, Al-Othman Z A, et al. Analyst, 2012, 137(18): 4309
52. [52]
  [52] Wang N N, He S W, Yan W W, et al. J Appl Polym Sci, 2013, 128(1): 741
53. [53]
  [53] Safavi A, Maleki N, Doroodmand M M. Anal Chim Acta, 2010, 675(2): 207
54. [54]
  [54] Katz E, Willner I. Chem Phys Chem, 2004, 5(8): 1084
55. [55]
  [55] Zhong Y Y, Zhou W F, Zhu H B, et al. Anal Chim Acta, 2011, 686(1/2): 1
56. [56]
  [56] Zhong Y Y, Zhou W F, Zeng X L, et al. Chin Chem Lett, 2011, 22(4): 461
57. [57]
  [57] Stadermann M, McBrady A D, Dick B, et al. Anal Chem, 2006, 78(16): 5639
58. [58]
  [58] Reid V R, Stadermann M, Bakajin O, et al. Talanta, 2009, 77(4): 1420
59. [59]
  [59] Fonverne A, Ricoul F, Demesmay C, et al. Sensor Actuat B: Chem, 2008, 129(2): 510
60. [60]
  [60] Fonverne A, Demesmay C, Ricoul F, et al. Sensor Actuat A: Phys, 2011, 167(2): 517
61. [61]
  [61] Yu J G, Huang D S, Huang K L, et al. Chin J Chem, 2011, 29(5): 893
1. [1]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
2. [2]
  Shunü Peng , Huamin Li , Zhaobin Chen , Yiru Wang . Simultaneous Application of Multiple Quantitative Analysis Methods in Gas Chromatography for the Determination of Active Ingredients in Traditional Chinese Medicine Preparations. University Chemistry, 2025, 40(10): 243-249. doi: 10.12461/PKU.DXHX202412043
3. [3]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
4. [4]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
5. [5]
  Qiuting Zhang , Fan Wu , Jin Liu , Zian Lin . Chromatographic Stationary Phase and Chiral Separation Using Frame Materials. University Chemistry, 2025, 40(4): 291-298. doi: 10.12461/PKU.DXHX202405174
6. [6]
  Ying Chen , Ronghua Yan , Weiyan Yin . Research Progress on the Synthesis of Metal Single-Atom Catalysts and Their Applications in Electrocatalytic Hydrogen Evolution Reactions. University Chemistry, 2025, 40(9): 344-353. doi: 10.12461/PKU.DXHX202503066
7. [7]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
8. [8]
  Zelin Wang , Gang Liu , Mengran Wang , Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . Application of Instrumental Analysis in the Detection of Organic Components in Liquor. University Chemistry, 2025, 40(11): 318-326. doi: 10.12461/PKU.DXHX202502077
9. [9]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
10. [10]
  Yifan Xie , Liyun Yao , Ruolin Yang , Yuxing Cai , Yujie Jin , Ning Li . Exploration and Practice of Online and Offline Hybrid Teaching Mode in High-Performance Liquid Chromatography Experiment. University Chemistry, 2025, 40(11): 100-107. doi: 10.12461/PKU.DXHX202412133
11. [11]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-0. doi: 10.3866/PKU.WHXB202310024
12. [12]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
13. [13]
  Runjie Li , Hang Liu , Xisheng Wang , Wanqun Zhang , Wanqun Hu , Kaiping Yang , Qiang Zhou , Si Liu , Pingping Zhu , Wei Shao . 氨基酸的衍生及手性气相色谱分离创新实验. University Chemistry, 2025, 40(6): 286-295. doi: 10.12461/PKU.DXHX202407059
14. [14]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
15. [15]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
16. [16]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
17. [17]
  Houjin Li , Lin Wu , Xingwen Sun , Yuan Zheng , Zhanxiang Liu , Shuanglian Cai , Ying Xiong , Guangao Yu , Qingwen Liu , Jie Han , Xin Du , Chengshan Yuan , Qihan Zhang , Jianrong Zhang , Shuyong Zhang . Basic Operations and Specification Suggestions for Organic Chemical Chromatography Experiments. University Chemistry, 2025, 40(5): 93-105. doi: 10.12461/PKU.DXHX202408100
18. [18]
  Shuhong Xiang , Lv Yang , Yingsheng Xu , Guoxin Cao , Hongjian Zhou . Selective electrosorption of Cs(Ⅰ) from high-salinity radioactive wastewater using CNT-interspersed potassium zinc ferrocyanide electrodes. Acta Physico-Chimica Sinica, 2025, 41(9): 100097-0. doi: 10.1016/j.actphy.2025.100097
19. [19]
  Chen Pu , Daijie Deng , Henan Li , Li Xu . Fe_0.64Ni_0.36@Fe₃NiN Core-Shell Nanostructure Encapsulated in N-Doped Carbon Nanotubes for Rechargeable Zinc-Air Batteries with Ultralong Cycle Stability. Acta Physico-Chimica Sinica, 2024, 40(2): 2304021-0. doi: 10.3866/PKU.WHXB202304021
20. [20]
  Ke Qiu , Fengmei Wang , Mochou Liao , Kerun Zhu , Jiawei Chen , Wei Zhang , Yongyao Xia , Xiaoli Dong , Fei Wang . A Fumed SiO₂-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries. Acta Physico-Chimica Sinica, 2024, 40(3): 2304036-0. doi: 10.3866/PKU.WHXB202304036

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(324)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142