Citation: LI Xuemin, JIA Guangqun, CAO Yanzhong, ZHANG Jinjie, WANG Lei, SUN Huiyuan. Simultaneous determination of δ¹³C values of glycerol and ethanol in wine by liquid chromatography coupled with isotope ratio mass spectrometry[J]. Chinese Journal of Chromatography, ;2013, 31(12): 1201-1205. doi: 10.3724/SP.J.1123.2013.07027 shu

Simultaneous determination of δ¹³C values of glycerol and ethanol in wine by liquid chromatography coupled with isotope ratio mass spectrometry

1.
Qinhuangdao Entry-Exit Inspection and Quarantine Bureau, Qinhuangdao 066004, China

Corresponding author: LI Xuemin,
Received Date: 17 July 2013
Available Online: 29 August 2013
Fund Project:

A novel procedure was established for the characterization of δ¹³C values of glycerol and ethanol in wine by liquid chromatography-isotope ratio mass spectrometry (LC-IRMS). Several parameters influencing the separation of glycerol and ethanol from wine matrix were optimized. The precision and accuracy of the proposed method were 0.15‰ to 0.26‰ and 0.11‰ to 0.28‰, respectively. The results obtained for 40 wine samples displayed that the δ¹³C value of glycerol ranged from -26.87‰ to -32.96‰ and that of ethanol ranged from -24.06‰ to -28.29‰. Close correlations (R=0.82) were obtained between the δ¹³C values of glycerol and ethanol. The proposed method didn't need complex sample treatment, and the δ¹³C values of glycerol and ethanol in wine can be simultaneously determined, thus improving the method in terms of simplicity and speed compared with traditional methods.
- liquid chromatography-isotope ratio mass spectrometry (LC-IRMS),
- δ¹³C values,
- glycerol,
- ethanol,
- wine
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沈阳化工大学材料科学与工程学院沈阳 110142

Simultaneous determination of δ13C values of glycerol and ethanol in wine by liquid chromatography coupled with isotope ratio mass spectrometry

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通讯作者: 陈斌, bchen63@163.com

Simultaneous determination of δ¹³C values of glycerol and ethanol in wine by liquid chromatography coupled with isotope ratio mass spectrometry