Citation: YANG Lili, WANG Meifei, HU Enyu, LIU Jing, WU Lijuan. Determination of 21 phenolic compounds in soil by ultrasonic extraction-gas chromatography[J]. Chinese Journal of Chromatography, ;2013, 31(11): 1081-1086. doi: 10.3724/SP.J.1123.2013.05005 shu

Determination of 21 phenolic compounds in soil by ultrasonic extraction-gas chromatography

1.
Nanjing Environmental Monitoring Center, Nanjing 210013, China

Corresponding author: YANG Lili,
Received Date: 2 May 2013
Available Online: 20 July 2013
Fund Project: 国家环境保护标准制修订项目(2009-1045) (2009-1045)南京市建设委员会科技项目(200717J). (200717J)

An effective method was developed to determine phenolic compounds in soil by ultrasonic extraction-gas chromatography (GC). The soil sample was extracted with methylene dichloride-hexane (2:1, v/v) for 3 min with the extraction temperature lower than 50 ℃ for 3 times. The extract was purified by alkaline aqueous solution (pH >12), and the phenolic compounds were dissolved in aqueous solution. After the organic solution was discarded, the aqueous solution was adjusted to pH<3 and subsequently extracted with methylene dichloride-ethyl acetate (4:1, v/v) twice. The analytes were determined by GC-FID and quantified by external standard method. The limits of quantification for all tested phenolic compounds were 0.01-0.06 mg/kg in about 10 g soil samples. The recoveries were between 62.9% and 111.4% with the relative standard deviations (RSDs) in the range of 4.3%-24.0% (n=6). The results showed that this method is sensitive, accurate, and suitable for the determination of the 21 phenolic compounds in soil.
- ultrasonic extraction,
- gas chromatography (GC),
- phenolic compounds,
- soil
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